Q. As the number of —OH groups increases in hypophosphorus acid phosphorus acid and phosphoric acid the acidic strength

A) Increases
B) Decreases
C) Remains nearly same
D) Remains appropriately same
Explanation

(c)
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Although thre number of –OH groups is increasing in $H_{3}PO_{2}$ ( 1 OH group), $H_{3}PO_{3}$ (2 OH group) and $H_{3}PO_{4}$ (3 OH group), yet acidity does not increase much. This is due to the fact that the number of unprotonated oxygen, responsible for enhancement of acidity due to inductive effect, remains the same, as a result dissociation constant also remains nearly same.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.