(c)
Magnetic moment $(\mu) = \sqrt{n(n + 2)}\$BM$\$where,$\$'$n$' is the number of unpaired electrons.
_{23}$V^{2 +}$=[Ar]$3d^{3}$ ($n$=3)
_{24}${Cr}^{2 +}$=[Ar]$3d^{4}$ ($n$=4)
_{25}${Mn}^{2 +}$=[Ar]$3d^{5}$ ($n$=5)
_{26}${Fe}^{2 +}$=[Ar]$3d^{6}$ ($n$=4)
Hence magnetic moment will be maximum for ${Mn}^{2 +}$ (equal to 5.92 BM).