(d)
Ti, Zr and Hf belong to IV B group of Periodic Table and in a group atomic radii increases on moving down. However, the transition metals of $4d$-series have nearly the same radii as metals of $5d$-series. Hence the order of atomic radii is
$Ti < Zr \approx HF\$
Due to nearly equal atomic radii, Zr and Hf are called chemical twins.