(b)
Argentite is an ore of Ag having composition ${Ag}_{2}S$. It dissolves in NaCN due to formation of soluble complex.
${Ag}_{2}S\ + \ 4NaCN \longrightarrow \ 2Na\lbrack Ag(CN)_{2}\rbrack\ + \ NaCl$
$\therefore$ NaCN is used to dissolve argentite.