Q. Tautomerism is not exhibited by :

A) $C_{6}H_{5} - CH = CH - OH$
B) [image:9_image29.emf]
C) [image:9_image30.emf]
D) [image:9_image31.emf]
Explanation

(b)
(a) Shows tautomerism since aldehydes are more stable than vinyl alcohols
$C_{6}H_{5} - CH = CHOH\ \leftrightarrow C_{6}H_{5}CH_{2} - CH_{2} - CH_{2} = 0$
(b) Does not show tautomerism because it does not have hydrogens at $\alpha$-positions
( c ) Shows tautomerism because enol form is stabilized by H-bonding
[image:9_image158.emf]
(d) Shows tautomerism because enol form is stabilized by aromatic character
[image:9_image159.emf]

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.