(b)
When ligands are arranged in ascending order of crystal field splitting energy, $\mathrm{\Delta}$, they produce a spectrochemical series.
In comparison to $H_{2}O,\ Cl$ is strong $\sigma$-donor and good $\pi$-acceptor, therefore it is a strong ligand than $H_{2}O$. Hence, in the spectrochemical series Cl is above than water.