(b)
Configuration of $Mn^{2 +}$ is
[Ar]$3d^{5}$
According to CFSE (crystal field stabilisation energy), in excited state of $Mn^{2 +}$ ion, three electrons go in $t_{2g}$ level $\left( d_{xy},d_{yz}\ and\ d_{zx} \right)$ and two electrons go in $e_{g}$ level ($d_{z^{2}}$ and $D_{x^{2} - y^{2}}$).