Q. Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives

A) 2, 4, 6-trinitrobenzene
B) o-nitrophenol
C) p-nitrophenol
D) Nitrobenzene
Explanation

(b)
[image:11_image283.emf]
First sulphonation is the means to block para position and to reduce the reactivity of
phenolic ring against strong oxidising agent $HNO_{3}$. (The use of conc. $HNO_{3}$ over phenol cause the oxidation of ring mainly). The strong acidic medium in second step cause desulphonation (ipso mechanism) also.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.