Q. Among the following, which is least acidic?

A) Phenol
B) o-cresol
C) p-nitrophenol
D) p-chlorophenol
Explanation

(b)
When an electron attracting group (like $–NO_{2}, - CI$) is attached to the phenol ring, it stabilises the negative charge on the oxygen of phenoxide ion. Due to this reason acidic character of phenol increases. But when an electron donating group (like $–CH_{3}$) is attached to the phenol ring, it destabilises the ring and hence, acidic character of phenol decreases. Thus, the correct order of acidic character is
p- nitrophenol > p-chlorophenol > phenol > o-cresol.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.