(c)
Only aldehydes and ketones react with 2, 4-dinitrophenyl hydrazine to give orange coloured ppt. This reaction is used as test for carbonyl group. Alcohols does not give this reaction.
[image:12_image512.emf]
Choice (a), (b) and (d) are carbonyl compounds and they react with 2,4-dnitreophenyl hydrazine $CH_{3}OH$[choice(c)] doesn’t have carbonyl group.
$\therefore CH_{3}OH$[choice (c)] doesn’t react with 2,4-dinitrophenyl hydrazine.