Q. In a Cannizaro’s reaction, the combination not possible is

A) HCHO + HCHO
B) $C_{6}H_{5}CHO + HCHO$
C) $CH_{3}CHO + HCHO$
D) [image:12_image178.emf]
Explanation

(c)
As Cannizaro reaction is shown by aldehydes lacking $\alpha$-hydrogen, hence the combination $CH_{3}CHO + HCHO$ is not possible
$HCHO + HCHO\ \underset{\mathrm{\Delta}}{\overset{\ \ NaOH\ \ }{\rightarrow}}CH_{3}OH + HCOO^{-}Na^{+}$
$C_{6}H_{5}CHO + HCHO\underset{\mathrm{\Delta}}{\overset{\ \ NaOH\ \ }{\rightarrow}}C_{6}H_{5}{CH}_{2}OH + {HCOO}^{-}{Na}^{+}$
[image:12_image579.emf]

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.