Q. The compound obtained when acetaldehyde reacts with dilute aqueous sodium hydroxide exhibits

A) Geometrical isomerism
B) Optical isomerism
C) Neither optical nor geometrical isomerism
D) Both optical and geometrical isomerism
Explanation

(b)
When acetaldehyde is treated with aqueous sodium hydroxide solution, it sundergoes aldol condensation (because of the presence of $\alpha -$H atom) as.
$\begin{matrix}
\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \\
CH_{3}CHO + HCH_{2}CHO\ \underset{NaOH}{\overset{\ \ \ Dil.aqueous\ \ \ \ }{\rightarrow}}CH_{3}CH
\end{matrix}$
$*$
$= CHCHO\ \overset{\ \ \ \ \mathrm{\Delta}\ \ \ \ }{\leftarrow}\ \ CH_{3}CH(OH)CH_{2}CHO$
(shows geometrical isomerism)
aldol
(shows optical isomerism)

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.