Q. Which of the following functional groups, cannot be reduced to alcohol using $NaBH_{4}$ in ethanolic solution?

A) $R - O - R$
B) $RCOCl$
C) $R - COOH$
D) $R - CHO$
Explanation

(a)
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ O$
||
Only compounds having $–C -$ are reduced to alcohol using $NaBH_{4}$in ethanolic solution.
$\ \ \ \ \ \ \ \ \ O\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ O$
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$R - C - l,R - C - OH,$
$\ \ \ \ \ \ \ \ \ O\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ O$
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$R - C - H$ have$- C -$
$\therefore$They are reduced to alcohols by reaction with ethanolic $NaBH_{4}$solution.
O
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$\therefore R - O - R$ does not have$- C -$ group.
$\therefore$It cannot be reduced to alcohol by alcoholic solution of $NaBH_{4}$.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.