Q. Alkyl cyanides undergo Stephen reduction to produce

A) Aldehyde
B) Secondary amine
C) Primary amine
D) amide
Explanation

(a)
An alkyl cyanide is dissolved in ether or better in ethyl formate or ethyl acetate, and reduced with $SnCI_{2}$ and $HCI$ and then steam distilled. The whole process is called Stephen reaction. In this process alkyl cyanide is reduced to aldehyde.
$CH_{3} - C \equiv NH = 2\lbrack H\rbrack + HCI\underset{ether}{\overset{{SnCI}_{2} + HCI}{\rightarrow}}$
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There is no analogous method for the preparation of ketones.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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