(d)
Carbylamine reaction is given by aliphatic and aromatic primary amine.
$CH_{3}CN$ does not give carbylamine reaction with chloroform because it is not an amine.
$CH_{3}CN$ undergoes acidic hydrolysis to give carboxylic acid.
$CH_{3}CN\overset{H_{2}O/H^{+}}{\rightarrow}CH_{3}CONH_{2}\overset{H_{2}O/H^{+}}{\rightarrow}CH_{3}COOH + NH_{3}$
acetic acid
$CH_{3}CN$ undergoes alkaline hydrolysis to give salt of carboxylic acis.
$CH_{3}CN\underset{H_{2}O}{\overset{NaOH}{\rightarrow}}CH_{3}CONH_{2}\underset{H_{2}O}{\overset{NaOH}{\rightarrow}}CH_{3}COONa + NH_{3}$
Sodium acetate
$CH_{3}CN$ tautomerises to give methyl isocyanide.
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