(b)
Tertiary amines, due to lack of H-atom, attached directly with N, does not react with benzene sulphonyl chloride $(C_{6}H_{5}SO_{2}CI)$, i.e., Hinsberg’s reagent.${\ \left( C_{2}H_{5} \right)}_{3}N$ is a tertiary amine, so does not react with $C_{6}H_{5}SO_{2}CI$.