Q. Hydrolysis of sucrose with dilute aqueous sulphuric acid yields

A) 1 : 1D-(+)–glucose; D-(-)-fructose
B) 1 : 2D-(+)–glucose; D-(-)-fructose
C) 1 : 1D-(-)–glucose; D-(+)-fructose
D) 1 : 2D-(-)–glucose ; D-(+)-fructose
Explanation

(a)
On hydrolysis with dilute aqueous sulphuric acid, sucrose gives a equimolar mixture of D-(+) glucose and D-(-)-fructose.
$C_{12}H_{22}O_{11} + \ H_{2}O\ \overset{\ \ \ \ \ H_{2}SO_{4}\ \ \ \ \ }{\rightarrow}\ {\ \ C}_{6}H_{12}O_{6}\ \ \ + \ \ \ \ C_{6}H_{12}O_{6}\$
Sucrose D-(+)glucose D-(+)fructose
1
Sucrose is dextrorotatory but after hydrolysis gives dextrorotatory glucose and laevorotatory fructose, laevorotatory fructose is more, so the mixture is laevorotatory.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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