Q. A decapeptide (mol. wt. 796) on complete hydrolysis gives glycine (mol. wt. 75), alanine and phenylalanine. Glycine contributes 47% to the total weight of the hydrolysed products. The number of glycine units present in the decapeptide is

A) 3
B) 4
C) 5
D) 6
Explanation

(d)
A decapeptide has nine peptide (amide) linkage as
[image:14_image58.emf]
Therefore, on hydrolysis, it will absorb nine water molecules.
Hence, total mass of hydrolysis product
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ = 796 + 18 \times 9 = 958$
$\Rightarrow$ mass of glycine in hydrolysis product
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ = \frac{958 \times 47}{100} = 450$
$\Rightarrow$ number of glycine molecule in one molecule of decapeptide
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ = \frac{450}{75} = 6$

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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