(c)
Suppose $a = 2,\ b = 1$
$\sin{\theta = \frac{2^{2} + 1^{2}}{2^{2} - 1} = \frac{5}{3} > 1}$, which is not possible
$\sec{\theta = \frac{4}{5} < 1}$, which is not possible
$\tan{\theta = 45}$, which is possible
$\cos{\theta = \frac{7}{3} > 1}$, which is not possible