(b)
Here, $\alpha + \beta = \frac{5}{6}$ and $\alpha\beta = \frac{1}{6}$
$\therefore\ \tan^{- 1}{\alpha + \tan^{1}{\beta = \tan^{- 1}\left( \frac{\alpha + \beta}{1 - \alpha\beta} \right)}}$
$= \tan^{- 1}\left( \frac{\frac{5}{6}}{1 - \frac{1}{6}} \right)$
$= \tan^{- 1}{1 = \frac{\pi}{4}}$