(d)
The given equation is
$pqx^{2} - (p + q)^{2}x + (p + q)^{2} = 0$
$\therefore\ \ \ \ x = \frac{(p + q)^{2} \pm \sqrt{(p + q)^{4} - 4pq(p + q)^{2}}}{2pq}$
$\Rightarrow \ \ \ x = \frac{(p + q)^{2} \pm (p^{2} - q^{2})}{2pq}$
$\Rightarrow \ \ \ \ x = \frac{p + q}{q},\ \frac{p + q}{p}$