(d)
$\because$ Line perpendicular to $3x + y = 3$ is $x - 3y = \lambda$
Also, it passes through (2, 2)
$\therefore 2 - 6 = \lambda\ \ \Rightarrow \ \lambda = - 4$
$\therefore$ Equation of line is
$x - 3y = - 4$ …(i)
Hence, $y$-intercept $= \frac{- 4}{- 3} = \frac{4}{3}$