(a)
The equation of required line is
${3x}^{2} + 4xy - 4x(2x + y) + {(2x + y)}^{2} = 0$
$\Rightarrow \ {3x}^{2} + 4xy - 8x^{2} - 4xy + 4x^{2} + y^{2} + 4xy = 0$
$\Rightarrow \ - x^{2} + y^{2} + 4xy = 0$
(Coefficient of $x^{2}) +$(Coefficient of $y^{2}) = - 1 + 1 = 0$
$\therefore$ Lines are mutually perpendicular.
$ie,\ Angle\ between\ lines\ is\frac{\pi}{2}.$