(d)
Since, both the points lie on the circle. At (5, 12), equation of tangent is
$5x + 12y = 169$ …(i)
At $(12,\ - 5)$, equation of tangent is
$12x - 5y = 169$ …(ii)
It is clear that Eqs. (i) and (ii) are perpendicular to each other.
Hence, angle between them is $90{^\circ}$