(d)
Equation of pair of tangents is
$\left( a^{2} - 1 \right)y^{2} - x^{2} + 2ax - a^{2} = 0$
If $\theta$ be the angle between the tangents, then
$\tan\theta = \frac{2\sqrt{(h^{2} - ab)}}{a + b}$
$= \frac{2\sqrt{- \left( a^{2} - 1 \right)( - 1)}}{a^{2} - 2}$
$= \frac{2\sqrt{a^{2} - 1}}{a^{2} - 1}$
$\because\ \theta$ lies in II quadrant, the $\tan\theta < 0$
$\therefore\ \frac{2\sqrt{a^{2} - 1}}{a^{2} - 2} < 0$
$\Rightarrow \ \ a^{2} - 1 > 0$ and $a^{2} - 2 < 0$
$\Rightarrow \ \ 1 < a^{2} < 2$
$\Rightarrow \ \ a \in \left( - \sqrt{2},\ - 1 \right) \cup (1,\ \sqrt{2})$