(a)
Let $y = m_{1}x$ and $y = m_{2}x$ be a pair of conjugate diameters of an ellipse $\frac{x^{2}}{a^{2}} + \frac{y^{2}}{b^{2}} = 1$ and let $P(a\cos{\theta,\ {b\ sin}{\theta)}}$ and $Q(a\cos{\phi,\ b}\sin{\phi)}$ be ends of these two diameters. Then,
$m_{1}m_{2} = - \frac{b^{2}}{a^{2}}$
$\Rightarrow \frac{{b\ sin}\theta - 0}{a\cos\theta - 0} \times \frac{{b\ sin}{\phi - 0}}{a\cos\phi - 0} = - \frac{b^{2}}{a^{2}}$
$\Rightarrow \sin\theta\sin\phi = - \cos\theta\cos\phi$
$\Rightarrow \cos{(\theta} - \phi) = 0$
$\Rightarrow \theta - \phi = \pm \frac{\pi}{2}$