(d)
Since, 44 kg is replaced by 46 kg and 27 kg is replaced by 25 kg, then the given series becomes 31, 35, 25, 29, 32, 43, 37, 41, 34, 28, 36, 46, 45, 42, and 30.
On arranging this series in ascending order, we get
25, 28, 29, 30, 31, 32, 34, 35, 36, 37, 41, 42, 43, 45, 46.
Total numbers of students are 15, therefore middle term is 8^{th} whose corresponding value is 35.