(c)
The required probability $= 1 -$ probability of equal number of heads and tails.
Out of $2n$ tossed $n$ times heads and $n$ times tails.
$= 1 - {\ ^{2n}C}_{n}\left( \frac{1}{2} \right)^{n}\left( \frac{1}{2} \right)^{2n - n\ }$
$= 1 - \frac{(2n)!}{n!n!}\left( \frac{1}{2} \right)^{2n} = 1 - \frac{(2n)!}{(n!)^{2}} \bullet \frac{1}{4^{n}}$