(a)
$P(E) = P(X = 2) + P(X = 3) + P(X = 5) + P(X = 7)$
$= 0.23 + 0.12 + 0.20 + 0.07 = 0.62$
$P(F) = P(X = 1) + P(X = 2) + P(X = 3)$
$= 0.15 + 0.23 + 0.12 = 0.5$
$P(E \cap F) = P(X = 2) + P(X = 3)$
$= 0.23 + 0.12 = 0.35$
$\therefore\ P(E \cup F) = P(E) + P(F) - P(E \cap F)$
$= 0.62 + 0.5 - 0.35 = 0.77$