(b)
Let $E_{1}$ denote the event of travelling by train and $E_{2}$ denote the event travelling by plane.
$P\left( E_{1} \right) = \frac{2}{3},\ P\left( E_{2} \right) = \frac{1}{5}$
$P\left( E_{1} \cup E_{2} \right) = P\left( E_{1} \right) + P\left( E_{2} \right)$
$= \frac{2}{3} + \frac{1}{5} = \frac{13}{15}$