(c)
Given that, $\theta = \tan^{- 1}a\ and\ \phi = \tan^{- 1}b$
And $ab = - 1$
$\therefore\tan{\theta\tan\phi} = ab = - 1$
$\Rightarrow \tan{\theta = - \cot\phi}$
$\Rightarrow \tan{\theta = \tan\left( \frac{\pi}{2} + \phi \right)}$
$\Rightarrow \theta - \phi$= $\frac{\pi}{2}$