(d)
The point of intersection of given curve is (0, 1). On differentiating given curves, we get
$\frac{dy}{dx} = a^{x}$log $a,\frac{dy}{dx} = b^{x}$ log $b$
$\Rightarrow \ \ \ \ \ m_{1} = a^{x}$ log $a,m_{2} = b^{x}$log $b$
At (0,1) $m_{1} =$log $a,m_{2} =$log $b$
$\therefore\ \ \ \$tan$\theta = \frac{m_{1} - m_{2}}{1 + m_{1}m_{2}}$
$\Rightarrow \ \ \ \ \ \ \theta = \tan^{- 1}\left| \frac{\log a - \log b}{1 + \log a\log b} \right|$