(d)
Given, $\left| \mathbf{\ }\overrightarrow{\mathbf{a}}\mathbf{+}\overrightarrow{\mathbf{b}} \right| < 1$
$\Rightarrow \ \sqrt{1 + 1 + 2\cos{2\alpha}} < 1$
$\Rightarrow \ \sqrt{2(1 + \cos{2\alpha)}} < 1$
$\Rightarrow \ \sqrt{4\cos^{2}\alpha} < 1$
$\Rightarrow {|cos}{\alpha| < \frac{1}{2}}$
$\Rightarrow \frac{\pi}{3} < \alpha < \frac{2\pi}{3}\ \ (\because 0 \leq \alpha \leq \pi)$