(a)
$2\overrightarrow{\mathbf{OA}} + 3\overrightarrow{\mathbf{OB}} = 2\left( \overrightarrow{\mathbf{OC}} + \overrightarrow{\mathbf{CA}} \right) + 3\left( \overrightarrow{\mathbf{OC}} + \overrightarrow{\mathbf{CB}} \right)$
$= 5\overrightarrow{\mathbf{OC}} + 2\overrightarrow{\mathbf{CA}} + 3\overrightarrow{\mathbf{CB}}$
$= 5\overrightarrow{\mathbf{OC}}\ \ \ \ \left\lbrack \because 2\overrightarrow{\mathbf{CA}} = - 3\overrightarrow{\mathbf{CB}} \right\rbrack$