(d)
Since, $|\overrightarrow{\mathbf{a}} + \overrightarrow{\mathbf{b}}|^{2} = |\overrightarrow{\mathbf{a}}|^{2} + |\overrightarrow{\mathbf{b}}|^{2} + 2\ \left| \overrightarrow{\mathbf{a}} \right||\overrightarrow{\mathbf{b}}|cos\ \theta$
$\Longrightarrow (\sqrt{7})^{2} = (3\sqrt{3})^{2} + 4^{2} + 2(3\sqrt{3})^{2}(4)\cos\theta$
$\Longrightarrow 7 = 27 + 16 + 24\sqrt{3}\cos\theta$
$\Longrightarrow \cos{\theta = - \sqrt{3}}/2$
$\Longrightarrow \ \theta = 150{^\circ}$