(a)
We know that the position vector of the centroid of the triangle is
$\frac{\overrightarrow{\mathbf{a}} + \overrightarrow{\mathbf{b}} + \overrightarrow{\mathbf{c}}}{3}\ \$
Since, the triangle is an equilateral, therefore the orthocentre coincides
With the centroid and hence,
$\frac{\overrightarrow{\mathbf{a}} + \overrightarrow{\mathbf{b}} + \overrightarrow{\mathbf{c}}}{3} = \overrightarrow{\mathbf{0}}$
$\Longrightarrow \ \overrightarrow{\mathbf{a}} + \overrightarrow{\mathbf{b}} + \overrightarrow{\mathbf{c}} = \overrightarrow{\mathbf{0}}$