(a)
Since, $\overrightarrow{\mathbf{a}} = 8\overrightarrow{\mathbf{b}}\ and\ \overrightarrow{\mathbf{c}} = - 7\overrightarrow{\mathbf{b}}$
$\therefore\ \overrightarrow{\mathbf{a}}$ is parallel to $\overrightarrow{\mathbf{b}}\$and $\overrightarrow{\mathbf{c}}\$is anti-parallel to $\overrightarrow{\mathbf{b}}$
$\Longrightarrow \ \overrightarrow{\mathbf{a}}\$and $\overrightarrow{\mathbf{c}}$ are anti-parallel
$\Longrightarrow \$Angle between $\overrightarrow{\mathbf{a}}$ and $\overrightarrow{\mathbf{c}}$ is $\pi$