(c)
Given $|\overrightarrow{\mathbf{a}} + \overrightarrow{\mathbf{b}}|^{2} = |\overrightarrow{\mathbf{a}} - \overrightarrow{\mathbf{b}}|^{2}$
$\Longrightarrow 4\overrightarrow{\mathbf{a}} \bullet \overrightarrow{\mathbf{b}} = 0 \Longrightarrow \ \overrightarrow{\mathbf{a}} \bullet \overrightarrow{\mathbf{b}} = 0$
So, angle between them is $90{^\circ}$