(c)
Given, $\overrightarrow{\mathbf{a}} \bullet \overrightarrow{\mathbf{b}} = \overrightarrow{\mathbf{a}} \bullet \overrightarrow{\mathbf{c}} = 0$
Now, $|\overrightarrow{\mathbf{a}} + \overrightarrow{\mathbf{b}} + \overrightarrow{\mathbf{c}}|^{2} = |{\overrightarrow{\mathbf{a}}|}^{2} + \left| \overrightarrow{\mathbf{b}} \right|^{2} + \left| \overrightarrow{\mathbf{c}} \right|^{2} + 2(\overrightarrow{\mathbf{a}} \bullet \overrightarrow{\mathbf{b}} + \overrightarrow{\mathbf{b}} \bullet \overrightarrow{\mathbf{c}} + \overrightarrow{\mathbf{c}} \bullet \overrightarrow{\mathbf{a}})$
$= {(1)}^{2} + {(1)}^{2} + {(1)}^{2} + 2\left( 0 + \left| \overrightarrow{\mathbf{b}} \right|\left| \overrightarrow{\mathbf{c}} \right|cos\ \frac{\pi}{3} + 0 \right)$
$= 3 + 2 \times 1 \times 1 \times \frac{1}{2} = 4$
$\Longrightarrow \left| \overrightarrow{\mathbf{a}} + \overrightarrow{\mathbf{b}} + \overrightarrow{\mathbf{c}} \right| = \pm 2$