(a)
Given projection of $\overrightarrow{\mathbf{a}}\ on\ \overrightarrow{\mathbf{b}} = |\overrightarrow{\mathbf{a}} \times \overrightarrow{\mathbf{b}}|$
$\Longrightarrow \ \frac{\overrightarrow{\mathbf{a}} \bullet \overrightarrow{\mathbf{b}}}{|\overrightarrow{\mathbf{b}}|} = |\overrightarrow{\mathbf{a}} \times \overrightarrow{\mathbf{b}}|$
$\Longrightarrow \ \frac{\left| \overrightarrow{\mathbf{a}} \right||\overrightarrow{\mathbf{b}}|\ cos\ \theta}{|\overrightarrow{\mathbf{b}}|} = \left| \overrightarrow{\mathbf{a}} \right||\overrightarrow{\mathbf{b}}|\ sin\ \theta$
$\Longrightarrow \tan\theta = \frac{1}{|\overrightarrow{\mathbf{b}}|}$
$\Longrightarrow \tan\theta = \frac{1}{\frac{1}{3}\sqrt{1^{2} + 1^{2} + 1^{2}}}$
$\Longrightarrow \tan{\theta = \sqrt{3}}$
$\Longrightarrow \ \theta = \frac{\pi}{3}$