(d)
Given, $\overrightarrow{\mathbf{a}} \times \overrightarrow{\mathbf{b}} = \overrightarrow{\mathbf{0}}\ and\overrightarrow{\mathbf{a}} \bullet \overrightarrow{\mathbf{b}} = 0$
$\Longrightarrow \ \overrightarrow{\mathbf{a}}$ is parallel to $\overrightarrow{\mathbf{b}}$ and $\overrightarrow{\mathbf{a}}$ is perpendicular to $\overrightarrow{\mathbf{b}}$ which is possible only if
$\overrightarrow{\mathbf{a}} = \overrightarrow{\mathbf{0}}\ \ or\ \overrightarrow{\mathbf{b}} = \overrightarrow{\mathbf{0}}$