(c)
Volume of parallelopiped,
$f(a) = \left| \begin{matrix}
1 & a & 1 \\
0 & 1 & a \\
a & 0 & 1
\end{matrix} \right| = 1 + a^{3} - a$
$Now,\ \ \ f^{'}(a) = 3a^{2} - 1$
$\Longrightarrow f^{''}(a) = 6a$
Put $f^{'}(a) = 0$
$\Longrightarrow a \neq \pm \frac{1}{\sqrt{3}}$
Which shows $f(a)$ is maximum at
$a = \frac{1}{\sqrt{3}}\ and\ maximum\ at\$
$a = - \frac{1}{\sqrt{3}}$