Q.
Phosphoric acid ionizes in three steps with their ionization constant values $K_{a_1}, K_{a_2}$ and $K_{a_3}$, respectively, while K is the overall ionization constant. Which of the following statements are true?
A. $\log K = \log K_{a_1} + \log K_{a_2} + \log K_{a_3}$
B. $H_3PO_4$ is stronger acid than $H_2PO_4^-$ and $HPO_4^{2-}$.
C. $K_{a_1} > K_{a_2} > K_{a_3}$
D. $K_{a_1} = \frac{K_{a_3} + K_{a_2}}{2}$
Choose the correct answer from the options given below:
A) A and B only
B) A and C only
C) B, C and D only
D) A, B and C only
Explanation
[Solution by Claude - not from source] $K=K_{a_1}K_{a_2}K_{a_3}$, so A is true. Each successive ionization is harder, so $K_{a_1}>K_{a_2}>K_{a_3}$ (C true) and $H_3PO_4$ is the strongest acid of the three (B true). D is false. Answer (4).
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.