Q.
Mechanism of a hypothetical reaction $X_2 + Y_2 \rightarrow 2XY$ is given below :
(i) $X_2 \rightarrow X + X$ (fast)
(ii) $X + Y_2 \rightleftharpoons XY + Y$ (slow)
(iii) $X + Y \rightarrow XY$ (fast)
The overall order of the reaction will be :
A) 1
B) 2
C) 0
D) 1.5
Explanation
[Solution] Rate = $k[X][Y_2]$ with $[X] \propto [X_2]^{1/2}$ from the fast equilibrium, so order = 1/2 + 1 = 1.5. Answer (4).
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.