Q.
For a given exothermic reaction, $K_p$ and $K'_p$ are the equilibrium constants at temperatures $T_1$ and $T_2$, respectively. Assuming that heat of reaction is constant in temperature range between $T_1$ and $T_2$, it is readily observed that :
A) $K_p > K'_p$
B) $K_p < K'_p$
C) $K_p = K'_p$
D) $K_p = \frac{1}{K'_p}$
Explanation
[Solution] For an exothermic reaction K decreases as temperature rises; taking $T_2 > T_1$, $K_p > K'_p$. (The key in the PDF gives (3), which is incorrect; standard solutions give (1).) Answer (1).
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.