[Solution from source] The n = 2 → 1 transition in hydrogen emits a 10.2 eV photon. Work function = 10.2 − 3.57 = 6.63 eV = 6.63 × 1.6 × 10⁻¹⁹ J. Threshold frequency ν₀ = φ/h = (6.63 × 1.6 × 10⁻¹⁹)/(6.63 × 10⁻³⁴) = 1.6 × 10¹⁵ Hz. Using the full 10.2 eV gives about 2.5 × 10¹⁵ Hz, which is the photon frequency, not the threshold. Answer (4).