[Solution from source] BaCl₂ is a salt of a strong acid and a strong base, so it does not hydrolyse and its solution is neutral (pH ≈ 7). BeCl₂ and AlCl₃ hydrolyse strongly to give acidic solutions, and LiCl is very slightly acidic due to the small, polarising Li⁺. So BaCl₂ has the highest pH. Answer (2).