[Solution from source] Iron(III) sulphate decomposes on heating: Fe₂(SO₄)₃ → Fe₂O₃ + 3SO₃. Sulphur with hot concentrated H₂SO₄ gives SO₂, H₂SO₄ with PCl₅ gives chlorosulphonic acid/sulphuryl chloride, and CaSO₄ with carbon is reduced to CaS or SO₂, not SO₃. Answer (3).