[Solution from source] [Ne]3s²3p³ is phosphorus: a small period-3 atom with a stable half-filled 3p subshell, so it has the highest ionization energy here. [Ar]3d¹⁰4s²4p³ (arsenic) is also half-filled but larger, and the 3p¹ and 3p² atoms (Al, Si) lose electrons more easily. Answer (4).