Q. Benzene reacts with CH₃Cl in the presence of anhydrous AlCl₃ to form:

A) Chlorobenzene
B) Benzyl chloride
C) Xylene
D) Toluene
Explanation

[Solution from source] This is Friedel–Crafts alkylation: AlCl₃ generates CH₃⁺ which substitutes on the ring, giving C₆H₅CH₃ (toluene). Chlorobenzene would need Cl₂, benzyl chloride needs side-chain chlorination of toluene, and xylene needs a second methylation. Answer (4).

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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